Bimetallic Pt-Pd nanostructures supported on MoS₂ as an ultra-high performance electrocatalyst for methanol oxidation and nonenzymatic determination of hydrogen peroxide

The authors report on a composite based electrocatalyst for methanol oxidation and H₂O₂ sensing. The composite consists of Pt nanoparticles (NPs), Pd nanoflakes, and MoS₂. It was synthesized by chemical reduction followed by template-free electro-deposition of Pt NPs. FESEM images of the Pd nanoflakes on the MoS₂ reveal nanorod-like morphology of the Pd NPs on the MoS₂ support, whilst FESEM images of the Pt-Pd/MoS₂ composite show Pt NPs in high density and with the average size of ~15 nm, all homogeneously electrodeposited on the Pd-MoS₂ composite. A glassy carbon electrode (GCE) was modified with the composite to obtain an electrode for methanol oxidation and H₂O₂ detection. The modified GCE exhibits excellent durability with good catalytic efficiency (the ratio of forward and backward peak current density, I_f/I_b, is 3.23) for methanol oxidation in acidic medium. It was also used to sense H₂O₂ at an applied potential of -0.35 V vs. Ag|AgCl which can be detected with a 3.4 μM lower limit of detection. The sensitivity is 7.64 μA μM^-1 cm^-2 and the dynamic range extends from 10 to 80 μM. This enhanced performance can be explained in terms of the presence of higher percentage of metallic 1T phase rather than a semiconducting 2H phase in MoS₂. In addition, this is a result of the high surface area of MoS₂ with interwoven nanosheets, the uniform distribution of the Pt NPs without any agglomeration on MoS₂ support, and the synergistic effect of Pt NPs, Pd nanoflakes and MoS₂ nanosheets. In our perception, this binder-free nano-composite has promising applications in next generation energy conversion and in chemical sensing. Graphical abstract A composite consisting of palladium nanoflakes and molybdenum disulfide was decorated with platinum nanoparticles and then placed on a glassy carbon electrode which is shown to be a viable electrocatalyst for both methanol oxidation and detection of hydrogen peroxide.