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Updated: Feb 6, 2026

Surface Properties of Synthesized Nanoporous Carbon and Silica Matrices
Published on: March 27, 2019
Two- and three-dimensional hybrid zinc phosphites: syntheses, structures and photoluminescence properties
Song-De Han1, Xiu-Rong Zhang, Jie Pan
1College of Chemistry and Chemical Engineering, Qingdao University, Shandong 266071, P. R. China. gmwang_pub@163.com.
Abstract:
Two zinc-phosphites modified by a rigid amine 3,5-bis(imidazole-1-yl)pyridine (BIP), [Zn2(HPO3)2(BIP)]·H2O (1) and [Zn3(HPO3)3(BIP)(H2O)]·H2O (2), were solvothermally prepared. Compound 1 possesses a zincophosphite layer decorated by BIP moieties via coordinating to intralayer Zn(ii) ions. Compound 2 features a 3D frame with a pillar-layer structure, in which the organic BIP pillars the inorganic zincophosphite layer via coordinating to interlayer Zn(ii) ions. The structural diversity from a 2D layer to a 3D frame was mainly attributable to the different bridging modes of BIP in the process of assembly. Their temperature-dependent photoluminescence properties have also been studied.
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