Theoretical investigation of heterogeneous wettability in porous media using NMR

It is highly important to understand the heterogeneous wettability properties of porous media for enhanced oil recovery (EOR). However, wettability measurements are still challenging in directly investigating the wettability of porous media. In this paper, we propose a multidimensional nuclear magnetic resonance (NMR) method and the concept of apparent contact angles to characterize the heterogeneous wettability of porous media. The apparent contact angle, which is determined by both the wetting surface coverage and the local wettability (wetting contact angles of each homogeneous wetting regions or wetting patches), is first introduced as an indicator of the heterogeneous wettability of porous media using the NMR method. For homogeneously wetting patches, the relaxation time ratio T₁/T₂ is employed to probe the local wettabiity of wetting patches. The T₂ - D is introduced to obtain the wetting surface coverage using the effective relaxivity. Numerical simulations are conducted to validate this method.