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Opening two benzene rings on trichalcogenasumanenes toward high performance organic optical-limiting materials
Xueqing Hou1, Jibin Sun, Zhe Liu
1State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Tianshui Southern Road 222, Lanzhou, Gansu Province, P. R. China. shaoxf@lzu.edu.cn.
Abstract:
Two flanking benzene rings on trichalcogenasumanenes (1a/1b) were opened upon oxidation, and the successive ring reconstruction afforded donor-acceptor type polycycles containing diimide units (3a/3b). 3a and 3b show excellent optical-limiting properties superior to C60.
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