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Cu(OAc)
Tubai Ghosh1, Pintu Maity1, Brindaban C Ranu1
1Department of Organic Chemistry , Indian Association for the Cultivation of Science , Jadavpur, Kolkata 700032 , India.
Abstract:
An efficient method for the C(sp2) amidation of 8-aminoquinoline benzamide by acyl azide in the presence of copper acetate has been achieved via C-H activation. Interestingly, the loading of copper acetate has a strong influence on the outcome of the reaction. The use of 1 equiv of copper acetate produces the corresponding aroyl amide, whereas the use of 2 equiv led to acetyl amide. A series of substituted benzoyl and acetyl amides has been obtained.
