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Electron Configuration of Multielectron Atoms03:26

Electron Configuration of Multielectron Atoms

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The alkali metal sodium (atomic number 11) has one more electron than the neon atom. This electron must go into the lowest-energy subshell available, the 3s orbital, giving a 1s22s22p63s1 configuration. The electrons occupying the outermost shell orbital(s) (highest value of n) are called valence electrons, and those occupying the inner shell orbitals are called core electrons. Since the core electron shells correspond to noble gas electron configurations, we can abbreviate electron...
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An atom comprises protons and neutrons, which are contained inside the dense, central core called the nucleus, with electrons present around the nucleus. Taking into account the wave–particle duality of electrons and the uncertainty in position around the nucleus, quantum mechanics provides a more accurate model for the atomic structure. It describes atomic orbitals as the regions around the nucleus where electrons of discrete energy exist, characterized by four quantum...
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Overview
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An atomic orbital represents the three-dimensional regions in an atom where an electron has the highest probability to reside. The radial distribution function indicates the total probability of finding an electron within the thin shell at a distance r from the nucleus. The atomic orbitals have distinct shapes which are determined by l, the angular momentum quantum number. The orbitals are often drawn with a boundary surface, enclosing densest regions of the cloud.
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Electron Carriers

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Electron carriers can be thought of as electron shuttles. These compounds can easily accept electrons (i.e., be reduced) or lose them (i.e., be oxidized). They play an essential role in energy production because cellular respiration is contingent on the flow of electrons.
Over the many stages of cellular respiration, glucose breaks down into carbon dioxide and water. Electron carriers pick up electrons lost by glucose in these reactions, temporarily storing and releasing them into the electron...
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Hybridization of Atomic Orbitals I03:24

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The mathematical expression known as the wave function, ψ, contains information about each orbital and the wavelike properties of electrons in an isolated atom. When atoms are bound together in a molecule, the wave functions combine to produce new mathematical descriptions that have different shapes. This process of combining the wave functions for atomic orbitals is called hybridization and is mathematically accomplished by the linear combination of atomic orbitals. The new orbitals that...
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Related Experiment Video

Updated: Feb 5, 2026

Picometer-Precision Atomic Position Tracking through Electron Microscopy
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Picometer-Precision Atomic Position Tracking through Electron Microscopy

Published on: July 3, 2021

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Dissociative electron attachment studies with hyperthermal Rydberg atoms.

S Buathong1, F B Dunning1

  • 1Department of Physics and Astronomy, Rice University, Houston, Texas 77005-1892, USA.

The Journal of Chemical Physics
|September 17, 2018
PubMed
Summary
This summary is machine-generated.

Hyperthermal Rydberg atoms offer detailed insights into dissociative electron capture dynamics. Collisions reveal sensitivity to intermediate ion properties and Rydberg atom electron distribution, enhancing understanding of electron transfer reactions.

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Area of Science:

  • Atomic and Molecular Physics
  • Chemical Physics
  • Quantum Mechanics

Background:

  • Previous studies explored dissociative electron capture using low-to-intermediate principal quantum number (n) potassium Rydberg atoms.
  • Velocity distributions of ion-pair states provided initial insights into reaction dynamics.

Purpose of the Study:

  • To investigate the potential of hyperthermal Rydberg atoms for a more detailed exploration of reaction dynamics in electron capture processes.
  • To demonstrate this approach using helium Rydberg atoms and a specialized computational model.

Main Methods:

  • Development and application of a semi-classical Monte Carlo collision code.
  • Simulation of collisions between helium Rydberg atoms and electron-attaching targets.
  • Analysis of the sensitivity of collision outcomes to various atomic and ionic properties.

Main Results:

  • Collision outcomes are significantly influenced by the lifetime and decay energetics of the intermediate negative ion formed.
  • The radial electron probability density distribution, specifically the orbital angular momentum (ℓ) value, of the Rydberg atom critically affects the reaction.
  • Hyperthermal Rydberg atom collisions provide a more nuanced view compared to lower-energy studies.

Conclusions:

  • Hyperthermal Rydberg atoms represent a powerful tool for dissecting complex electron transfer and dissociative electron capture mechanisms.
  • Understanding the role of the Rydberg electron's spatial distribution (ℓ value) is crucial for accurate modeling.
  • This methodology opens new avenues for studying fundamental atomic and molecular collision processes.