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Evaluation of different LSC methods for 222Rn determination in waters
Jovana Nikolov1, Ivana Stojković2, Nataša Todorović1
1University of Novi Sad, Faculty of Sciences, Department of Physics, Novi Sad, Serbia.
This study calibrates liquid scintillation counting (LSC) for measuring radon in water, evaluating two methods and four cocktails. Both LSC methods proved effective for accurate radon detection in water samples.
Area of Science:
- Environmental Science
- Analytical Chemistry
- Radiochemistry
Background:
- Radon-222 (Rn) monitoring in water is crucial for geological surveys and health hazard assessments.
- Liquid scintillation counting (LSC) is a preferred method for waterborne Rn due to its efficiency and automation capabilities.
Purpose of the Study:
- To calibrate the Qunatulus 1220™ liquid scintillation counter for Rn in water measurements.
- To evaluate one-phase and two-phase LSC methods for optimal Rn detection in water.
- To assess the performance of four different scintillation cocktails for Rn analysis.
Main Methods:
- Calibration of LSC using calibration factor (CF) dependence on Pulse Shape Analysis (PSA).
- Evaluation of one-phase and two-phase LSC methods using four scintillation cocktails (Ultima Gold AB, High Efficiency Mineral Oil Scintillator, Opti-Fluor O, Ultima Gold F).
- Comparison of LSC results with alpha spectrometry (RAD7) using 226Ra spiked and environmental water samples.
Main Results:
- Both one-phase and two-phase LSC methods are suitable for Rn in water measurement with proper calibration.
- All tested scintillation cocktails yielded very low Minimal Detectable Activity (MDA) values (<0.1 Bq/L for 300 min).
- LSC demonstrated good accuracy and precision when compared to alpha spectrometry.
Conclusions:
- The Qunatulus 1220™ LSC system, when properly calibrated, is a reliable tool for quantifying radon in various water matrices.
- The choice of scintillation cocktail and method (one-phase or two-phase) can be optimized based on specific analytical needs.
- The study confirms the low detection limits achievable with LSC for environmental radon monitoring.
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