Reversible dispersion and precipitation of single-walled carbon nanotubes using a pH-responsive rigid surfactant
Zhaolan Zhai1, Xinyan Yan2, Ji Xu2
1Institute of Chemical Industry of Forest Products, CAF, National Engineering Lab. for Biomass Chemical Utilization, Key and Open Lab. of Forest Chemical Engineering, SFA, Key Lab. of Biomass Energy and Material, Nanjing 210042, Jiangsu Province, China. rxping2001@163.com and Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Nanjing 210037, China.
Abstract:
A pH-responsive rigid surfactant derived from rosin was used to disperse and precipitate single-walled carbon nanotubes (SWNTs) in aqueous solution. The precipitated SWNTs could be re-dispersed by changing the pH without sonication owing to the hydrophobic steric layers formed by the rigid group and π-π interactions from the azobenzene group.
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