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Amide Coupling Reaction for the Synthesis of Bispyridine-based Ligands and Their Complexation to Platinum as Dinuclear Anticancer Agents
Published on: May 28, 2014
Expanded campestarene hosts for tetra- and dinuclear uranyl(vi) complexes
Mohammad T Chaudhry1, Francesco Lelj2, Mark J MacLachlan1
1Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, British Columbia V6T 1Z1, Canada. mmaclach@chem.ubc.ca.
Abstract:
The first expanded campestarenes based on a keto-enamine scaffold have been constructed using uranyl acetate as a template. Macrocycles with six and eight aryl rings in their backbone host dinuclear and tetranuclear uranium(vi) species, respectively. The complexes were characterized by SCXRD, FT-IR, UV-vis, and NMR spectroscopy, and DFT calculations corroborated their structures.
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