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Published on: July 10, 2015
A rare three-dimensional POM-based inorganic metal polymer bonded by CO2 with high catalytic performance for CO2
Weiwei Cheng1, Yun-Shan Xue, Xi-Ming Luo
1College of Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, P. R. China.
Abstract:
An exceedingly rare three-dimensional CO2-coordinated inorganic polyoxoanion was prepared by a hydrothermal synthesis reaction. The CO2 ligand connects with two Zn-ε-Keggin cores in a linear and symmetrical μ2-η2o,o coordination pattern with a C[double bond, length as m-dash]O bond length of 1.099(112) Å. The new compound reported here exhibits not only appealing structures but also high catalytic activity for the cycloaddition of carbon dioxide with epoxides.
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