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First report on solution processed α-Ce2S3 rectangular microrods: An efficient energy storage supercapacitive

Swapnil S Karade1, Akanksha Agarwal1, Bidhan Pandit1

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Chemically synthesized cerium sulfide (α-Ce2S3) microrods offer high performance for energy storage. These materials demonstrate excellent specific capacitance and electrochemical stability, paving the way for advanced energy storage devices.

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Nanotechnology

Background:

  • Developing efficient electrode materials is crucial for next-generation energy storage.
  • Chemical bath deposition (CBD) offers a scalable and cost-effective method for material synthesis.

Purpose of the Study:

  • To synthesize rectangular α-Ce2S3 microrods using a low-temperature CBD approach.
  • To investigate the structural, morphological, and electrochemical properties of the synthesized α-Ce2S3.

Main Methods:

  • Chemical bath deposition (CBD) for α-Ce2S3 microrod synthesis.
  • Structural, morphological, and surface wettability characterizations.
  • Electrochemical performance evaluation including specific capacitance and cycling stability.

Main Results:

  • Successfully synthesized rectangular α-Ce2S3 microrods via a facile CBD method.
  • Observed lower contact angle, reduced intrinsic resistance, and improved ion diffusion.
  • Achieved a specific capacitance of 726 F/g at 2 mV/s and 93% stability over 2000 cycles.

Conclusions:

  • The synthesized α-Ce2S3 microrods exhibit promising electrochemical properties for energy storage applications.
  • The unique morphology and surface properties contribute to enhanced electrochemical performance.
  • α-Ce2S3 is a viable candidate for next-generation energy storage devices.