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Electrospun Carbon Nanofiber/Boron Nitride Composites as Flexible Anodes for Lithium-Ion Batteries
Minghua Chen1, Shouzhi Zhang1, Jiawei Zhang1
1School of Electrical and Electronic Engineering, Key Laboratory of Engineering Dielectric and Applications (Ministry of Education) Harbin University of Science and Technology, Harbin 150080, P. R. China.
Abstract:
Flexible electrode material has bendable feature and can be directly applied as electrode without any additives and binders. In this study, flexible carbon nanofiber/boron nitride composites were prepared via a facile electrospinning and subsequent carbonization treatment for lithium ion battery. BN nanoparticles were uniformly dispersed in the nanofibers after an annealing temperature of 800 °C, and the diameters of nanofibers were at 100~450 nm range. The fabricated composites, used as binder-free anode materials, exhibited an impressive reversible capacity of 205 mAh·g-1 after 300 cycles at a current density of 100 mA·g-1. The electrodes still exhibited a specific capacity of 140 mAh·g-1 even at a higher current density of 1000 mA·g-1. The excellent electrochemical performance of the nanofiber/boron nitride composites can be attributed to the unique structure of nanofibers and superior electrical conductivity.
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