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Updated: Feb 3, 2026

Molten-Salt Synthesis of Complex Metal Oxide Nanoparticles
Published on: October 27, 2018
Direct Synthesis and Pseudomorphic Transformation of Mixed Metal Oxide Nanostructures with Non-Close-Packed Hollow
Zhendong Liu1,2, Wenyang Zhao2, Prashant Kumar1
1Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN, 55455, USA.
Abstract:
While bottom-up syntheses of ordered nanostructured materials at colloidal length scales have been successful at producing close-packed materials, it is more challenging to synthesize non-close-packed (ncp) structures. Here, a metal oxide nanostructure with ncp hollow sphere arrays was synthesized by combining a polymeric colloidal crystal template (CCT) with a Pechini precursor. The CCT provided defined confinement through its tetrahedral (Td ) and octahedral (Oh ) voids where the three-dimensionally (3D) ordered, ncp hollow sphere arrays formed as a result of a crystallization-induced rearrangement. This nanostructure, consisting of alternating, interconnected large and small hollow spheres, is distinct from the inverse opal structures typically generated from these CCTs. The morphology of the ncp hollow sphere arrays was retained in pseudomorphic transformations involving sulfidation and reoxidation cycling despite the segregation of zinc during these steps.
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