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Updated: Feb 3, 2026

Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
Published on: May 12, 2023
Moderate supercritical synthesis as a facile route to mixed-valent uranium(iv,v) and (v,vi) silicates
Kristen A Pace1, Vladislav V Klepov, Gregory Morrison
1Department of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina 29208, USA. zurloye@mailbox.sc.edu.
Abstract:
Mixed-valent uranium(iv,v) and (v,vi) phases represent a unique subset of known uranium compounds. Efforts to develop our current understanding of these materials have pointed to hydrothermal methods as effective preparative techniques. Herein we report the successful use of moderate supercritical conditions for the synthesis of five new U(v) containing phases.
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