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Updated: Feb 3, 2026

Fabrication of 1-D Photonic Crystal Cavity on a Nanofiber Using Femtosecond Laser-induced Ablation
Published on: February 25, 2017
Structural evolution and effective improvement of emission quantum yields for silicon nanocrystals synthesized by
Jianjun Wang1, Yingxiong Zhang1, Huilian Hao1
1College of Material Engineering, Shanghai University of Engineering Science, 333 Long Teng Road, Shanghai 201620, People's Republic of China.
Abstract:
Stable luminescent colloidal silicon (Si) nanocrystals (NCs) with sufficient surface protection are prepared through femtosecond laser ablation in organic solvent containing diverse concentrations of HF solution. The average size of Si NCs shows the decreasing tendency from 6.5 to 2.7 nm when the concentration of HF varies from 0 to 11.1 vol% (volume ratio). In line with the structural evolution, UV-visible absorption, photoluminescence (PL) excitation spectra, and time-resolved PL, we propose that room temperature blue emission peaks at 412 and 440 nm originate from alkyl-related radiative recombination centers. The enhanced PL quantum yield of colloidal Si NCs from 16.3% to 76.5% has been attributed to the effective passivation and suppression of non-radiative defect centers with increasing HF concentration from 0 to 11.1 vol%.
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