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Updated: Feb 3, 2026

Molten-Salt Synthesis of Complex Metal Oxide Nanoparticles
Published on: October 27, 2018
Correlating thermochromic and mechanochromic phosphorescence with polymorphs of a complex gold(i) double salt with
Qi Liu1, Mo Xie, Xiaoyong Chang
1Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry and the University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100190, P. R. China. chenyong@mail.ipc.ac.cn.
Abstract:
A complex [Au(NHC)2][Au(C[triple bond, length as m-dash]N)2] double salt exhibits polymorphic crystalline structures with distinct phosphorescence and variations at AuAu distances and ligand-ligand torsion angles. This serves as a model system correlating aurophilicity and low-energy charge-transfer electronic transitions and helps to understand the thermochromism and mechanochromism of the gold(i) complexes.
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