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Solid Oxide Electrochemical Systems: Material Degradation Processes and Novel Mitigation Approaches.

Michael Reisert1, Ashish Aphale2, Prabhakar Singh3

  • 1Department of Materials Science and Engineering, University of Connecticut, Storrs, CT 06269, USA. michael.reisert@uconn.edu.

Materials (Basel, Switzerland)
|November 8, 2018
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Summary

Solid oxide electrochemical systems offer efficient energy production but face material degradation. This review details degradation processes and mitigation strategies for enhanced longevity and performance.

Keywords:
corrosionelectrodeelectrode poisoninginterconnectoxide scalesolid oxide

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Energy Systems

Background:

  • Solid oxide electrochemical systems (SOFCs, SOECs, OTMs) provide clean energy and fuel via ceramic oxides.
  • These systems offer stability, fuel flexibility, and high efficiency but are limited by harsh operating conditions.
  • Material degradation under high temperatures and reactive atmospheres impacts long-term viability.

Purpose of the Study:

  • To review degradation processes affecting solid oxide electrochemical systems.
  • To discuss degradation mechanisms in system components and materials.
  • To present state-of-the-art mitigation technologies for improved longevity.

Main Methods:

  • Literature review of degradation phenomena in solid oxide electrochemical systems.
  • Analysis of material corrosion and degradation mechanisms.
  • Compilation of current mitigation techniques and technologies.

Main Results:

  • Identified key degradation processes impacting solid oxide materials.
  • Discussed specific degradation mechanisms relevant to system components.
  • Highlighted advanced strategies to minimize material degradation.

Conclusions:

  • Material degradation is a critical challenge for solid oxide electrochemical systems.
  • Understanding degradation mechanisms is crucial for developing durable materials.
  • Mitigation technologies are essential for extending system operational life and efficiency.