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Household solid fuel burning emission characterization and activity levels in India
Shamsh Pervez1, Madhuri Verma1, Suresh Tiwari2
1School of Studies in Chemistry, Pandit Ravishankar Shukla University, Raipur, Chhattisgarh 492010, India.
The Science of the Total Environment
|November 18, 2018
Summary
Household solid fuel combustion in India releases significant PM2.5, carbon, and ionic species. Coal balls exhibit the highest PM2.5 and organic carbon emissions, while dung cakes and crop residues are key sources of ionic compounds.
Area of Science:
- Environmental Science
- Atmospheric Chemistry
- Public Health
Background:
- Household solid fuel combustion is a major source of air pollution in India.
- Understanding emission factors (EFs) is crucial for air quality management.
- Various solid fuels like coal balls (CB), fuel wood (FW), dung cakes (DC), and crop residues (CR) are commonly used.
Purpose of the Study:
- To determine emission factors for PM2.5, carbon fractions, major ions, and elemental species from common Indian household solid fuels.
- To identify key emission indicators for different fuel types.
- To estimate the contribution of these fuels to India's annual emission budget.
Main Methods:
- Field sampling during actual household cooking practices across 10 Indian states.
- Analysis of PM2.5, organic carbon (OC), elemental carbon (EC), major ions (K+, Ca2+, NH4+, SO42-, NO3-, Cl-), and elemental species (Al, Cr, Cu, Fe).
- Calculation of species-wise emission factors and annual emission estimates.
Main Results:
- Coal balls (CB) showed the highest EFs for PM2.5 (34.16 ± 10.1 g·kg-1) and OC (14.18 ± 5.8 g·kg-1).
- Dung cakes (DC) had the highest EF for EC (2.33 ± 1.4 g·kg-1), while crop residues (CR) showed high EF for K+ (1.03 ± 0.2 g·kg-1) and Cl- (0.69 ± 0.1 g·kg-1).
- Ionic EFs were generally higher for DC, CR, and mixed fuels (MF) compared to FW and CB. Ratios like K+/EC and Cl-/EC can indicate CR, while NH4+/EC indicates DC.
Conclusions:
- Household solid fuel combustion significantly contributes to India's annual PM2.5 (27%), OC (15%), and EC (4%) emissions.
- Specific ionic ratios serve as valuable tracers for identifying fuel types.
- Effective emission control strategies targeting these solid fuels are necessary to improve air quality in India.
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