Enhanced Red Emission in Er³⁺-Sensitized NaLuF₄ Upconversion Crystals via Energy Trapping

Luminescence efficiency of trivalent lanthanide-doped upconversion (UC) materials is significantly limited by luminescence concentration quenching. In this work, red UC emission is dramatically enhanced in Er³⁺-sensitized NaLuF₄ UC crystals through energy trapping under multiple excitation wavelengths. Cross-relaxation quenching and the energy migration to internal lattice defects are simultaneously suppressed by confining the excitation energy in the Er³⁺ activator after introducing the Tm³⁺ or Ho³⁺ energy trapping center. The enhanced red UC emission (Er³⁺: 660 nm) mainly comes from the effective excitation energy confinement by Tm³⁺ and Ho³⁺ trapping centers through an easy energy transfer between Er³⁺ and Tm³⁺/Ho³⁺: ⁴I_11/2 (Er³⁺) → ³H₅ (Tm³⁺) → ⁴I_13/2 (Er³⁺) and ⁴I_11/2 (Er³⁺) → ⁵I₆ (Ho³⁺) → ⁴I_13/2 (Er³⁺). It is found that the confining efficiency of excitation energy in Er³⁺-sensitized NaLuF₄ crystals is higher than that in Yb³⁺/Er³⁺ cosensitized NaLuF₄ crystals, and the luminescence efficiency of Er³⁺-sensitized NaLuF₄ crystals is much higher than that of Er³⁺-based host sensitization UC crystals (NaErF₄). Moreover, Er³⁺-sensitized UC particles can be efficiently excited by three different wavelengths (808, 980, and 1532 nm), indicating huge advantages for applications in bioimaging, anticounterfeiting, and solar cells.