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Published on: December 20, 2016
Micron-Sized Nanoporous Antimony with Tunable Porosity for High-Performance Potassium-Ion Batteries
Yongling An1, Yuan Tian1, Lijie Ci1
1SDU & Rice Joint Center for Carbon Nanomaterials, Key Laboratory for Liquid-Solid Structural Evolution & Processing of Materials (Ministry of Education), School of Materials Science and Engineering , Shandong University , Jinan 250061 , PR China.
Abstract:
Potassium-ion batteries (KIBs) are considered favorable candidates for post-lithium-ion batteries, a quality attributed to their low cost, abundance as a resource, and high working potential (-2.93 V for K+/K). Owning to its relatively low potassiation potential and high theoretical capacity, antimony (Sb) is one of the most favorable anodes for KIBs. However, the large volume changes during K-Sb alloying and dealloying causes fast capacity degradation. In this report, nanoporous Sb (NP-Sb) is fabricated by an environmentally friendly vacuum-distillation method. The NP-Sb is formed via evaporating low-boiling-point zinc (Zn). The byproduct Zn can be recycled. It is further found that the morphology and porosity can be controlled by adjusting Zn-Sb composition and distillation temperature. The nanoporous structure can accommodate volume expansion and accelerate ion transport. The NP-Sb anode delivers an improved electrochemical performance. These results suggest that the vacuum-distillation method may provide a direction for the green, large-scale, and tunable fabrication of nanoporous materials.
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