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Updated: Feb 1, 2026

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
Published on: March 24, 2018
Solvatochromism and fluorescence response of a halogen bonding anion receptor
Jiyu Sun1, Asia Marie S Riel1, Orion B Berryman1
1Department of Chemistry and Biochemistry, University of Montana, 32 Campus Drive, Missoula, MT 59812.
Abstract:
Herein, we present on two 2,6-bis(4-ethynylpyridinyl)-4-fluoroaniline receptors that display solvatochromic absorption and emission. Neutral derivatives displayed opposite solvatochromic behavior as compared to the alkylated receptors. Adding anions induced changes in the absorption and emission spectra. In general, the fluorescence of the halogen bonding receptor was quenched less efficiently when compared to the hydrogen bonding receptor.
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