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Synthesis of highly-soluble push-pull perylenemonoimide derivatives by regioselective peri-functionalization for
Dhananjaya Sahoo1, Vikas Sharma, Rupam Roy
1Department of Chemistry, Indian Institute of Science Education and Research Bhopal, Bhopal By pass Road, Bhauri, Bhopal-462066, Madhya Pradesh, India. chem.dsahoo@gmail.com akoner@iiserb.ac.in.
Abstract:
A regioselective synthetic protocol is developed via tetrabromination of perylenemonoimide (PMI) which leads to a series of PMI derivatives. The push-pull characteristics of these derivatives are established by spectroscopic and theoretical investigations. Finally, the semiconducting properties of the PMI dyes are utilized for the development of a switchable memory device.
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