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Observation of dynamic charge stripes in Tm0.19Yb0.81B12 at the metal-insulator transition
N E Sluchanko1,2, A N Azarevich1,2, A V Bogach1
1Prokhorov General Physics Institute of the Russian Academy of Sciences, Vavilov str. 38, Moscow 119991, Russia.
Abstract:
Accurate low temperature charge transport measurements in combination with high-precision x-ray diffraction experiments have allowed detection of the symmetry lowering in the single domain Tm0.19Yb0.81B12 crystals that belong to the family of dodecaborides with metal-insulator transition. Based on the fine structure analysis we discover the formation of dynamic charge stripes within the semiconducting matrix of Tm0.19Yb0.81B12. The charge dynamics in these conducting nano-size channels is characterized by broad-band optical spectroscopy that allowed estimating the frequency (~2.4 × 1011 Hz) of quantum motion of the charge carriers. It is suggested that cooperative Jahn-Teller effect in the boron sublattice is a cause of the large-amplitude rattling modes of the Tm and Yb ions responsible for the 'modulation' of the conduction band along one of the [Formula: see text] directions through the variation of 5d-2p hybridization of electron states.
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