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Self-assembly of platinum(ii) 6-phenyl-2,2'-bipyridine complexes with solvato- and iono-chromic phenomena
Jiangjun Chen1, Lei Ao, Chengpeng Wei
1CAS Key Laboratory of Soft Matter Chemistry, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, Anhui 230026, China. drfwang@ustc.edu.cn.
Chemical Communications (Cambridge, England)
|December 8, 2018
Abstract:
Mono- and di-nuclear organoplatinum(ii) monomers with cyclometalated 6-phenyl-2,2'-bipyridine ligands have been successfully constructed. These systems are capable of displaying intriguing solvato- and iono-chromic phenomena by elaborately manipulating non-covalent PtPt metal-metal and π-π stacking interactions for their self-assembly processes.