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BaPO3Cl: a Metal Phosphate Chloride with Infinite [PO3]∞ Chains
Jianghe Feng1, Chun Li Hu1, Yuan Lin1
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter , Chinese Academy of Sciences , Fuzhou 350002 , P. R. China.
Abstract:
We adopted a chemical substitution strategy to design a particular anionic structure with large optical anisotropy in phosphate. Specifically, we replaced one O2- in Ba3P3O10Cl by two Cl-, leading to the formation of a new compound of BaPO3Cl ( P21/ c). Notably, this compound is the first metal phosphate chloride featuring infinite [PO3]∞ chains, and it displays good chemical and thermal stability, as well as a short UV cutoff edge (<200 nm) and relatively large birefringence.
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