Cellulose Nanocrystal (CNC) Coatings with Controlled Anisotropy as High-Performance Gas Barrier Films
Reaz A Chowdhury1, Md Nuruddin1, Caitlyn Clarkson1
1School of Materials Engineering , Purdue University , 701 W. Stadium Ave ., West Lafayette , Indiana 47907 , United States.
Abstract:
Cellulose nanomaterials are promising materials for the polymer industry due to their abundance and renewability. In packaging applications, these materials may impart enhanced gas barrier performance due to their high crystallinity and polarity. In this work, low barrier to superior gas barrier pristine nanocellulose films were produced using a shear-coating technique to obtain a range of anisotropic films. Induction of anisotropy in a nanocellulose film can control the overall free volume of the system which effectively controls the gas diffusion path; hence, controlled anisotropy results in tunable barrier properties of the nanocellulose films. The highest anisotropy materials showed a maximum of 900-fold oxygen barrier improvement compared to the isotropic arrangement of nanocellulose film. The Bharadwaj model of nanocomposite permeability was modified for pure nanoparticles, and the CNC data were fitted with good agreement. Overall, the oxygen barrier performance of anisotropic nanocellulose films was 97 and 27 times better than traditional barrier materials such as biaxially oriented poly(ethylene terephthalate) (BoPET) and ethylene vinyl alcohol copolymer (EVOH), respectively, and thus could be utilized for oxygen-sensitive packaging applications.
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