Comparison of radioactive aerosol size distributions (Activity, number, mass, and surface area)

Information regarding the number, mass, and specific surface area distributions of aerosols is extremely important for assessments of exposure to radiation due to the intake of radioactive aerosols by inhalation. In this study, these distributions were compared with the activity size distributions for radon decay products. The experiments were conducted in a radon chamber under controlled conditions for the aerosol concentrations and with size distributions in the range from 5 nm to 10 µm. The activity size distributions of the aerosols were measured by using a diffusion battery and two types of cascade impactors. The aerosol concentrations during the experiments were in the range from 2 × 10³ to 2.5 × 10⁵ cm^-3. The measurements obtained with a diffusion battery demonstrated that at the low aerosol concentration, up to 80% of activity of the radon decay products was connected with aerosol particles with an activity median thermodynamic diameter (AMTD) ~1 nm (unattached fraction). After injecting the aerosols into the experimental chamber, the activity of the unattached fraction decreased to practically zero but we observed the presence of the activity of aerosols with AMTD values ~10-20 nm. After injecting the aerosols, the distribution of the aerosol specific surface area exhibited a bimodal distribution, where the median diameter in the accumulation mode was ~120 nm and the geometric standard deviation (GSD) was 1.3. The median diameter in the coarse mode changed with time due to the deposition of aerosols on the walls of the chamber, where it decreased from 5 µm (GSD = 1.6) at 15 min after injection to 2 µm (GSD = 2.5) at 120 min after injection. The distribution of the aerosol activity measured by the cascade impactor was virtually independent of the time from the moment when the aerosols were injected. The parameters used to assess the activity distribution comprised an activity median aerodynamic diameter (AMAD) ~500-650 nm and GSD = 1.5. Comparisons of the activity distributions with the distributions for the number, mass, and specific surface area showed that the closest correspondence was with the average distribution over the specific surface, whereas there were no exact correspondences with the other distributions.