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NMR Spectrometers: Radiofrequency Pulses and Pulse Sequences01:17

NMR Spectrometers: Radiofrequency Pulses and Pulse Sequences

1.8K
A pulse is a short burst of radio waves distributed over a range of frequencies that simultaneously excites all the nuclei in the sample. Upon passing a radio frequency pulse along the x-axis, the nuclei absorb energy corresponding to their Larmor frequencies and achieve resonance. This shifts the net magnetization vector from the z-axis toward the transverse plane. This angle of rotation of the magnetization vector, or the flip angle, is proportional to the duration and intensity of the pulse.
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Pulse01:16

Pulse

2.1K
When the heart pumps blood out, arterial elastic fibers play a crucial role in sustaining a high-pressure gradient. They expand to accommodate the received blood and then recoil - a process known as the pulse that can be either manually palpated or electronically quantified. Despite a reduction in its effect with increased distance from the heart, elements of the pulse's systolic and diastolic components persist, observable even at the arteriole level.
The pulse serves as a clinical...
2.1K
Pulse01:05

Pulse

3.7K
The pulse is one of the most fundamental physiological indicators of the body's cardiovascular health. It is the rhythmic expansion and contraction of the arterial walls in response to the pressure generated by the heart's pumping action.
Pulse Rate and its Significance
Pulse rate, often measured in beats per minute (bpm), reflects the heart rate (HR), which is influenced by numerous factors such as stress, physical activity, and hormonal changes. A normal resting adult pulse rate falls...
3.7K
Electron Paramagnetic Resonance (EPR) Spectroscopy: Organic Radicals01:17

Electron Paramagnetic Resonance (EPR) Spectroscopy: Organic Radicals

3.4K
Ideally, an unpaired electron shows a single peak in the EPR spectrum due to the transition between the two spin energy states. However, coupling interactions can occur between the spins of the unpaired electron and any neighboring spin-active nuclei. This hyperfine coupling results in hyperfine splitting, where the EPR signal is split into multiplets. The signals split into 2nI + 1 peaks, where n is the number of equivalent nuclei and I is the nuclear spin. These splitting patterns provide...
3.4K
Pulse Oximetry01:24

Pulse Oximetry

1.4K
Pulse oximetry, or SpO2, is a non-invasive method for continuously monitoring arterial oxygen saturation (SaO2). This procedure involves attaching a probe or sensor to the patient's fingertip, forehead, earlobe, or nose bridge. The sensor works by detecting changes in oxygen saturation levels through light signals generated by the oximeter and reflected by the pulsing blood under the probe.
Purpose
Average SpO2 values are greater than 95%. If the readings fall below 90%, it indicates that...
1.4K
Regulation of Pulse01:20

Regulation of Pulse

2.3K
Pulse regulation involves physiological mechanisms that ensure adequate blood flow throughout the body. The heartbeat, regulated by the autonomic nervous system, is influenced by hormonal balance, physical activity, and emotional state.
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Related Experiment Video

Updated: Jan 31, 2026

Generation and Coherent Control of Pulsed Quantum Frequency Combs
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Generation and Coherent Control of Pulsed Quantum Frequency Combs

Published on: June 8, 2018

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An X-band pulsed electron paramagnetic resonance spectrometer with time resolution improved by a

Zhifu Shi1, Shiwei Mu1, Xi Qin1

  • 1CAS Key Laboratory of Microscale Magnetic Resonance and Department of Modern Physics, University of Science and Technology of China, Hefei 230026, China.

The Review of Scientific Instruments
|January 3, 2019
PubMed
Summary

This study presents a novel X-band pulsed electron paramagnetic resonance (EPR) spectrometer. Its Field-Programmable-Gate-Array (FPGA) pulse generator enables precise microwave pulse control for advanced EPR experiments.

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Area of Science:

  • Spectroscopy
  • Quantum Electronics
  • Materials Science

Background:

  • Pulsed electron paramagnetic resonance (EPR) spectroscopy requires precise control over microwave (MW) pulse parameters.
  • Existing pulse generators may lack the necessary time resolution for advanced EPR techniques.
  • High-time-resolution control is crucial for observing fast dynamics and quantum phenomena in EPR.

Purpose of the Study:

  • To develop and characterize a novel X-band pulsed EPR spectrometer.
  • To implement a Field-Programmable-Gate-Array (FPGA) based pulse generator for enhanced time resolution.
  • To demonstrate the utility of the high-time-resolution capabilities through Rabi oscillation measurements.

Main Methods:

  • An X-band pulsed EPR spectrometer was constructed.
  • A custom FPGA-based pulse generator with eight channels was developed, offering 50 ps time resolution for pulse generation.
  • Microwave pulses were formed using PIN diode switches controlled by the FPGA, and signals were recorded using a digital storage oscilloscope.
  • Custom software was developed for system control and data processing.

Main Results:

  • The spectrometer successfully generated precisely controlled microwave pulses with 50 ps time resolution.
  • The FPGA-based pulse generator demonstrated reliable operation across eight independent channels.
  • Rabi oscillation measurements were performed, validating the spectrometer's high-time-resolution capabilities and suitability for advanced EPR studies.

Conclusions:

  • The developed X-band pulsed EPR spectrometer, driven by an FPGA pulse generator, offers unprecedented time resolution.
  • This advancement enables detailed investigation of fast spin dynamics and quantum coherent phenomena in various systems.
  • The system provides a powerful tool for researchers in fields requiring high-precision EPR measurements.