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An A-D-A'-D-A Conjugated Molecule Entailing Diazapentalene Unit for an n-Type Organic Semiconductor
Gaobo Lin1,2, Lingna Wang1,2, Yizhou Yang1,2
1Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic Solids, CAS Center of Excellence in Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P.R. China.
Abstract:
Conjugated molecules with low lying LUMO levels are demanding for the development of air stable n-type organic semiconductors. In this paper, we report a new A-D-A'-D-A conjugated molecule (DAPDCV) entailing diazapentalene (DAP) and dicyanovinylene groups as electron accepting units. Both theoretical and electrochemical studies manifest that the incorporation of DAP unit in the conjugated molecule can effectively lower the LUMO energy level. Accordingly, thin film of DAPDCV shows n-type semiconducting behavior with electron mobility up to 0.16 cm2 ⋅V-1 ⋅s-1 after thermal annealing under N2 atmosphere. Moreover, thin film of DAPDCV also shows stable n-type transporting property in air with mobility reaching 0.078 cm2 ⋅V-1 ⋅s-1 .