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Published on: October 17, 2011
Stepwise degradation of hydroxyl compounds to aldehydes via successive C-C bond cleavage
Mingyang Liu1, Zhanrong Zhang, Xiaojun Shen
1Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid and Interface and Thermodynamics, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Zhongguancun North First Street 2, 100190 Beijing, P. R. China. zhangzhanrong@iccas.ac.cn hanbx@iccas.ac.cn.
Abstract:
Stepwise degradation of hydroxyl compounds to aldehydes via successive cleavage of C-C bonds was achieved by using a bimetallic catalytic system (PdCl2 + CuCl) without any ligands and additives. The broad applicability is expanded to a diverse range of aromatic, aliphatic, primary and secondary alcohols, as well as lignin model compounds.
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