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Updated: Jan 9, 2026

Reductive Electropolymerization of a Vinyl-containing Poly-pyridyl Complex on Glassy Carbon and Fluorine-doped Tin Oxide Electrodes
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Published on: January 30, 2015

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Switching CO2 Electroreduction Pathways via Polyvinylpyrrolidone-Mediated Water Configuration Control

Yaoyu Yin1,2, Zhongnan Ling1, Keke Chai2,3

  • 1Beijing National Laboratory for Molecular Sciences, CAS Laboratory of Colloid and Interface and Thermodynamics, CAS Research/Education Centre for Excellence in Molecular Sciences, Centre for Carbon Neutral Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing, China, 100049.

Angewandte Chemie (International Ed. in English)
|December 4, 2025
PubMed
Summary

Adding trace amounts of polyvinylpyrrolidone (PVP) to electrolytes precisely controls CO2 electroreduction products. This method tunes the water configuration, selectively producing methane or multicarbon products with high efficiency.

Keywords:
CO2 electroreductionInterfacial water structurePolyvinylpyrrolidoneProduct selectivity switching

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