Multisegmented Metallic Nanorods: Sub-10 nm Growth, Nanoscale Manipulation, and Subwavelength Imaging

Multisegmented metallic nanorods (MS-M-NRs) have attracted increasing attention thanks to their integrated structures and complex functions. The integration of nanoscale segments in 1D enables maximum exposure of each segment and enhanced interaction between adjacent segments. Such structural integration will induce functional complexity in the nanorods, leading to superior properties for the individual components. Herein, recent progress on the development of MS-M-NRs is reviewed. Their precise fabrication, nanoscale manipulation, and subwavelength imaging, as well as simultaneous manipulation and imaging are discussed, respectively. Specifically, precise fabrication of MS-M-NRs focuses on porous anodic alumina (PAA) templated electrodeposition, which enables sub-10 nm growth of the segments and their interfaces/fronts. Nanoscale manipulation of MS-M-NRs introduces the fundamental methods that are employed for delicate movement control on the nanorods through internal or external stimulations. Subwavelength imaging of MS-M-NRs highlights the achievements on identification and location of constituent nanoscale segments/gaps based on their differences and interactions. Simultaneous manipulation and imaging of MS-M-NRs addresses the significance and potential applications of the nanorods with magnetic-plasmonic dual modulation. The development of MS-M-NRs will greatly contribute to materials science and nanoscience/nanotechnology.