Electrospun Nanobelt-Shaped Polymer Membranes for Fast and High-Sensitivity Detection of Metal Ions

Until now, no polymer nanobelt-shaped materials have been developed as electrochemical, optical, and mass sensors. In this work, we first develop polymer nanobelt-shaped membranes for fast and high-sensitivity detection of metal ions, which are fabricated by a new nanobelt-based processing method with simultaneous zein matrix cross-linking and curcumin cross-linking. Their morphologies, optimal detection pH, ion selectivity, and ion detection sensitivity are systematically analyzed. The limits of detection of electrospun curcumin-loaded zein membranes with a detection time of 0.5 h are as follows: cross-linked nanobelt-shaped membranes (0.3 mg/L) < uncross-linked nanobelt-shaped membranes (1 mg/L) ≈ cross-linked nanofibrous membranes (1 mg/L) < uncross-linked nanofibrous membranes (3 mg/L). The cross-linked nanobelt-shaped membranes are also applied to detect Fe³⁺ in drinking water and environmental water. Finally, the mechanisms of Fe³⁺ detection by these membranes are studied and discussed. The results demonstrate that the difference of limit of detection is dependent on if the curcumin sensor is cross-linked or not and the membrane nanostructures (nanobelts or nanofibers). Cross-linking produces stable sensor molecules on the surface and therefore induces low limits of detection. Compared with nanofibers, nanobelts have a higher surface-to-volume ratio and can have more sensor molecules on their surfaces and therefore have lower limits of detection. In addition, the as-prepared membranes had good membrane storage stability (at least 3 months at room temperature). All of these results suggest that cross-linked electrospun nanobelt-shaped membranes by a new nanobelt-based processing method are ideal platforms for sensing. We believe that they will attract increasing attention in scientific and engineering fields such as materials, environmental, and food science.