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Updated: Jan 30, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
High proton conduction in an excellent water-stable gadolinium metal-organic framework
Xiu-Shuang Xing1, Zhi-Hua Fu, Ning-Ning Zhang
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. gcguo@fjirsm.ac.cn mswang@fjirsm.ac.cn zhihuafu@fjirsm.ac.cn.
Abstract:
A new metal-organic framework with excellent water stability, {H[(N(CH3)4)2][Gd3(NIPA)6]}·3H2O (1, H2NIPA = 5-nitroisophthalic acid), displays a proton conductivity of 7.17 × 10-2 S cm-1 (at 75 °C and 98% relative humidity), which is among the highest values for proton-conducting MOFs.
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