Co₃O₄-CuCoO₂ Nanomesh: An Interface-Enhanced Substrate that Simultaneously Promotes CO Adsorption and O₂ Activation...

Nanomaterials are widely used as redox-type reaction catalysts, while reactant adsorption and O₂ activation are hardly to be promoted simultaneously, restricting their applications in many important catalytic fields such as preferential CO oxidation (CO-PROX) in H₂-rich stream. In this work, an interface-enhanced Co₃O₄-CuCoO₂ nanomesh was initially synthesized by a hydrothermal process using aluminum powder as a sacrificial agent. This nanomesh is systematically characterized by powder X-ray diffraction, scanning electron microscopy, transmission electron microscopy, N₂ adsorption, X-ray photoelectron spectroscopy, UV-vis absorption spectroscopy, Raman spectroscopy, X-ray absorption near-edge spectroscopy, hydrogen temperature-programmed reduction, and oxygen temperature-programmed desorption. It is demonstrated that the nanomesh possesses high-density nanopores, enabling a large number of CO adsorption sites exposed to the surface. Meanwhile, electron transfer from O^2- to Co³⁺/Co²⁺ and the weakened bonding strength of Co-O bond at surfaces promoted the oxygen activation and redox ability of Co₃O₄. When tested as a catalyst for CO-PROX, this nanomesh with an optimized pore structure and a surface electronic structure, exhibits a strikingly high catalytic oxidation activity at low temperatures as well as a broader operation temperature window (i.e., CO conversion >99.0%, 100-200 °C) in the CO selective oxidation reaction. The present finding should be highly useful in promoting the quest for better CO-PROX catalysts, a hot topic for proton exchange membrane fuel cells and automotive vehicles.