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Published on: December 25, 2016
Construction of Polynitro Compounds as High-Performance Oxidizers via a Two-Step Nitration of Various Functional
Gang Zhao1, Dheeraj Kumar1, Ping Yin1
1Department of Chemistry , University of Idaho , Moscow , Idaho 83844-2343 , United States.
Abstract:
An oxygen-rich energetic compound, 1,3-bis(trinitromethyl)-1,2,4-triazole (13), was obtained by a two-step nitration and found to have an excellent crystal density of 1.90 g/cm3 confirmed by X-ray single-crystal diffraction. This highly dense material, as a green energetic oxidizer, features an attractive positive oxygen balance, an acceptable sensitivity, and a good enthalpy of formation, making it a competitive replacement for AP.
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