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Parahydrogen-induced polarization with a metal-free P-P biradicaloid
Vladimir V Zhivonitko1, Jonas Bresien, Axel Schulz
1NMR Research Unit, University of Oulu, P.O. Box 3000, 90014 Oulu, Finland. vladimir.zhivonitko@oulu.fi.
Abstract:
Metal-free H2 activations are unusual but interesting for catalytic transformations, particularly in parahydrogen-based nuclear spin hyperpolarization techniques. We demonstrate that metal-free singlet phosphorus biradicaloid, [P(μ-NTer)]2, provides pronounced 1H and 31P hyperpolarization while activating the parahydrogen molecules. A brief analysis of the resulting NMR signals and the important kinetic parameters are presented.
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