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Diffusion01:12

Diffusion

217.9K
Diffusion is the passive movement of substances down their concentration gradients—requiring no expenditure of cellular energy. Substances, such as molecules or ions, diffuse from an area of high concentration to an area of low concentration in the cytosol or across membranes. Eventually, the concentration will even out, with the substance moving randomly but causing no net change in concentration. Such a state is called dynamic equilibrium, which is essential for maintaining overall...
217.9K
Diffusion01:21

Diffusion

6.4K
Diffusion is a type of passive transport. In passive transport, a substance tends to move from an area of high concentration to an area of low concentration until the concentration is equal across the space. For example, take the diffusion of substances through the air. When someone opens a perfume bottle in a room filled with people, the perfume is at its highest concentration in the bottle and is at its lowest at the edges of the room. The perfume vapor will diffuse, or spread away, from the...
6.4K
Spanning Openings in Brick Walls01:20

Spanning Openings in Brick Walls

570
In brick wall construction, supporting structures are crucial for openings like windows and doors to maintain the integrity and support the weight of the wall above. These supports include lintels, corbels, and arches, each serving specific structural purposes.
Lintels are primary supports used to span openings and can be crafted from materials such as reinforced concrete, steel-reinforced brick masonry, or simple steel angles. These are straightforward to install and are typically concealed...
570
Behavior of Gas Molecules: Molecular Diffusion, Mean Free Path, and Effusion03:48

Behavior of Gas Molecules: Molecular Diffusion, Mean Free Path, and Effusion

31.3K
Although gaseous molecules travel at tremendous speeds (hundreds of meters per second), they collide with other gaseous molecules and travel in many different directions before reaching the desired target. At room temperature, a gaseous molecule will experience billions of collisions per second. The mean free path is the average distance a molecule travels between collisions. The mean free path increases with decreasing pressure; in general, the mean free path for a gaseous molecule will be...
31.3K
Density00:56

Density

19.8K
Density is an important characteristic of substances, crucial in determining whether an object sinks or floats in a fluid. Its SI unit is kg/m3, and its cgs unit is g/cm3. The density of an object helps in identifying its composition, and also reveals information about the phase of the matter and its substructure. The densities of liquids and solids are roughly comparable, consistent with the fact that their atoms are in close contact. However, gases have much lower densities than liquids and...
19.8K
Facilitated Diffusion01:16

Facilitated Diffusion

1.3K
The plasma membrane, a critical structure in cellular biology, houses an array of transporters, or carrier proteins, interspersed within its lipid bilayer. These proteins play a crucial role in solute transport through facilitated diffusion, a form of passive diffusion that uses transporters to move the molecules across the membrane.
In this process, substrates such as organic compounds and ions interact with a transporter on one side, triggering conformational changes in proteins that enable...
1.3K

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Related Experiment Video

Updated: Jan 29, 2026

Single-Molecule Diffusion and Assembly on Polymer-Crowded Lipid Membranes
10:43

Single-Molecule Diffusion and Assembly on Polymer-Crowded Lipid Membranes

Published on: July 19, 2022

2.9K

Density fluctuations as door-opener for diffusion on crowded surfaces.

Ann-Kathrin Henß1, Sung Sakong2, Philipp K Messer1

  • 1Department of Chemistry, Ludwig-Maximilians-Universität München, Germany.

Science (New York, N.Y.)
|February 16, 2019
PubMed
Summary

Oxygen atoms diffuse rapidly on a CO-covered ruthenium surface, nearly as fast as on a clean surface. This surprising mobility is explained by a "door-opening" mechanism facilitating particle movement on adsorbates.

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Area of Science:

  • Surface science
  • Heterogeneous catalysis
  • Chemical kinetics

Background:

  • Understanding particle diffusion on catalyst surfaces with high adsorbate coverage is crucial for industrial processes.
  • Most adsorption sites being occupied poses challenges for modeling adsorbate mobility.

Purpose of the Study:

  • To investigate the diffusion dynamics of oxygen (O) atoms on a fully carbon monoxide (CO)-covered ruthenium (Ru)(0001) surface.
  • To elucidate the mechanism behind O atom diffusion under industrially relevant, high-coverage conditions.

Main Methods:

  • Utilized high-speed/variable-temperature scanning tunneling microscopy (STM) for atomic resolution.
  • Employed density functional theory (DFT) calculations to complement experimental observations.

Main Results:

  • Observed surprisingly fast diffusion of O atoms, comparable to diffusion rates on a clean Ru(0001) surface.
  • Atomically resolved trajectories revealed the dynamic movement of individual O atoms.
  • Identified a 'door-opening' mechanism responsible for facilitating O atom diffusion.

Conclusions:

  • The 'door-opening' mechanism, driven by CO layer density fluctuations, allows O atoms to move efficiently.
  • This mechanism explains the high mobility of O atoms even on a densely packed CO layer.
  • Provides critical insights into surface diffusion under realistic industrial catalytic conditions.