Mature landfill leachate treatment using sonolytic-persulfate/hydrogen peroxide oxidation: Optimization of process...

The suitability of stand-alone ultrasound (US) system, coagulation pre-treatment followed by US, hydrogen peroxide added US system (US-H₂O₂) and persulfate added US system (US-PS) for the treatment of matured landfill leachate was investigated. With US system, around 67% COD removal and an increase in BOD/COD ratio were observed (from 0.033 to 0.142) after 15 min at 30% US amplitude. However, the energy input required for landfill leachate treatment in US system was found to be very high due to the presence of fixed solids. Coagulation pretreatment using alum was carried out to improve the overall COD removal and reduce the cost of treatment. As a result, the COD removal was increased to 78% (42% in pretreatment and 36% in US) in 15 min. On the other hand, US-H₂O₂ and US-PS hybrid systems have shown significant improvement in COD removals (93% and 86%, respectively) from raw leachate after 15 min. Subsequently, a three factor (i.e. PS dose (mg/L), H₂O₂ dose (mol/L), and US amplitude (%)) 5-level design of experiment was used to maximize the COD removal efficiency by response surface methodology (RSM). The RSM model generated a quadratic equation to accurately analyze the influence of input variables on COD removal efficiency (R² of 0.92). A maximum COD removal of 98.3% was predicted using the model and the corresponding optimal experimental condition were identified as follows: PS dose ∼4700 mg/L, H₂O₂ dose ∼0.7 mol/L and US amplitude ∼49%. The overall observations reveals that PS and H₂O₂ coupled with US system has a great prospective to treat mature landfill leachate.