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Updated: Jan 29, 2026

Absolute Quantum Yield Measurement of Powder Samples
Published on: May 12, 2012
Full expectation-value statistics for randomly sampled pure states in high-dimensional quantum systems
Peter Reimann1, Jochen Gemmer2
1Fakultät für Physik, Universität Bielefeld, 33615 Bielefeld, Germany.
Randomly sampling vectors in high-dimensional spaces reveals that observable expectation values have a narrow, near-Gaussian peak but deviate in the tails. This finding is crucial for understanding quantum systems and statistical mechanics.
Area of Science:
- Quantum mechanics
- High-dimensional Hilbert spaces
- Statistical mechanics
Background:
- Understanding the distribution of expectation values is key in quantum mechanics.
- Random sampling from Hilbert spaces is a fundamental concept.
Purpose of the Study:
- To analyze the distribution of expectation values of arbitrary observables.
- To investigate deviations from Gaussian behavior in high dimensions.
Main Methods:
- Analytical calculations of expectation value distributions.
- Sampling normalized vectors from high-dimensional Hilbert spaces.
- Analysis of eigenvalue distributions satisfying Wigner's semicircle law.
Main Results:
- The distribution shows a narrow, approximately Gaussian peak.
- Significant deviations from Gaussian behavior are observed in the tails.
- For Wigner's semicircle law eigenvalues, a large deviation function reveals symmetric nonanalyticities.
Conclusions:
- The study provides a detailed characterization of expectation value distributions in quantum systems.
- The findings offer insights analogous to critical phenomena in thermodynamics.
- This work advances the understanding of random quantum states and observables.
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