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Updated: Jan 28, 2026

1,3,5-Triphenylbenzene and Corannulene as Electron Receptors for Lithium Solvated Electron Solutions
Published on: October 10, 2016
A general approach to non-fullerene electron acceptors based on the corannulene motif
Viktor Barát1, Maja Budanović, Dzeneta Halilovic
1Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21-Nanyang Link, 637371, Singapore. mstuparu@ntu.edu.sg.
Abstract:
Here, we show that oxidation of exo-cyclic sulfur atoms enhances the molecular reduction potential of non-planar polycyclic aromatic hydrocarbons and allows for a systematic bridging of the electron affinity gap between corannulene, a fragment of fullerene C60, and the prevalent fullerene-based electron acceptor phenyl-C61-butyric acid methyl ester (PCBM).
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