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Strapping a benzaldehyde-appended 2,2'-bis-dipyrrin Zn(ii) double-stranded helicate using imine bond formation
Fan Zhang1, Audrey Fluck, Stéphane A Baudron
1Laboratoire de Tectonique Moléculaire, UMR CNRS 7140, icFRC, Université de Strasbourg, F-67000, Strasbourg, France. sbaudron@unistra.fr hosseini@unistra.fr.
Dalton Transactions (Cambridge, England : 2003)
|March 1, 2019
Abstract:
A novel linear binuclear Zn(ii)/2,2'-bis-dipyrrin double-stranded helicate bearing peripheral p-benzaldehyde moieties has been strapped by formation of imine bonds upon reaction with m-xylylenediamine and characterized by 1H- and 13C-NMR spectroscopy, UV-Visible spectroscopy and high-resolution mass spectrometry.