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Published on: August 10, 2016
Self-enhancement of CO reversible absorption accompanied by phase transition in protic chlorocuprate ionic liquids
Zhuo-Heng Tu1, Yi-Yang Zhang, You-Ting Wu
1School of Chemistry and Chemical Engineering, Separation Engineering Research Center, Nanjing University, Nanjing 210093, P. R. China. ytwu@nju.edu.cn huxb@nju.edu.cn.
Abstract:
An efficient strategy for the high-capacity capture of CO is reported, and a phase change in protic chlorocuprate ionic liquids (PCILs) from liquid to solid is found during CO absorption. The highest CO capacity is 0.96 molCO molIL-1, being at least 150 times higher than that in [BMIM][PF6]. Both absorption and membrane permeation reveal that the PCILs are potential for the selective separation of CO from N2.
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