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Updated: Jan 28, 2026

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Transition Metal Free Monoclinic Eu8In17.33S34 and Its Anisotropic Photoelectronic Responses
Yang Chi1, Teng-Fei Jiang1, Huai-Guo Xue1
1School of Chemistry and Chemical Engineering , Yangzhou University , Yangzhou , Jiangsu 225002 , P. R. China.
Abstract:
Novel Eu8In17.33S34 (1) is obtained by a solid state reaction and its structure features three parallel slabs of [In9.33S18]∞, [Eu8]∞, and [In8S16]∞, together with defects in specific lattice sites. It is the first monoclinic ternary M8- mIn18- n Q34 ( M = Pb, Sn, Eu; Q = S, Se) phase member, and the modulation from the ultralong In-S bond and lattice site with strong antibonding effect results in the unique structure feature. Its single crystals show anisotropic conductivity and photoconductivity.
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