Active Site-Directed Tandem Catalysis on Single Platinum Nanoparticles for Efficient and Stable Oxidation of...

The application of tandem catalysis is rarely investigated in degrading organic pollutants in the environment. Herein, a tandem catalyst on single platinum (Pt) nanoparticles (Pt⁰ NPs) is prepared for the sequential degradation of formaldehyde (HCHO) to carbon dioxide gas [CO₂(g)] at room temperature. The synthesis approach includes coating of uniform Pt NPs on SrBi₂Ta₂O₉ platelets using a photoreduction process, followed by calcination of the sample in the atmosphere to tune partial transformation of Pt⁰ atoms to Pt²⁺ ions in the tandem catalyst. The conversion of HCHO to CO₂(g) is monitored by in situ Fourier transform infrared spectroscopy, which shows first conversion of HCHO to CO₃^2- ions onto Pt⁰ active sites and subsequently the conversion of CO₃^2- ions to CO₂(g) by neighboring Pt²⁺ species of the catalyst. The later process with Pt²⁺ species does not allow CO₃^2- poisoning of the catalyst. The enhanced activity of the prepared tandem catalyst to oxidize HCHO is maintained continuously for 680 min. Comparatively, the catalyst without Pt²⁺ shows activity for only 40 min. Additionally, the tandem catalyst presented herein performs better than the Pt/titanium dioxide (TiO₂) catalyst to degrade HCHO. Overall, the tandem catalyst may be applied to degrade organic pollutants efficiently.