New approaches to enhance pollutant removal in artificially aerated wastewater treatment systems

Freshwater ecosystems sustain human society through the provision of a range of services. However, the status of these ecosystems is threatened by a multitude of pressures, including point sources of wastewater. Future treatment of wastewater will increasingly require new forms of decentralised infrastructure. The research reported here sought to enhance pollutant removal within a novel wastewater treatment technology, based on un-planted, artificially aerated, horizontal subsurface flow constructed wetlands. The potential for these systems to treat de-icer contaminated runoff from airports, a source of wastewater that is likely to grow in importance alongside the expansion of air travel and under future climate scenarios, was evaluated. A new configuration for the delivery of air to aerated treatment systems was developed and tested, based on a phased-aeration approach. This new aeration approach significantly improved pollutant removal efficiency compared to alternative aeration configurations, achieving >90% removal of influent load for COD, BOD₅ and TOC. Optimised operating conditions under phased aeration were also determined. Based on a hydraulic retention time of 1.5 d and a pollutant mass loading rate of 0.10 kg d^-1 m^-2 BOD₅, >95% BOD₅ removal, alongside final effluent BOD₅ concentrations <21 mg L^-1, could be achieved from an influent characterised by a BOD₅ concentration > 800 mg L^-1. Key controls on oxygen transfer efficiency within the aerated treatment system were also determined, revealing that standard oxygen transfer efficiency was inversely related to aeration rate between 1 L and 3 L min^-1 and positively related to bed media depth between 1500 mm and 3000 mm. The research reported here highlights the potential for optimisation and subsequent widespread application of the aerated wetland technology, in order to protect and restore freshwater ecosystems and the services that they provide to human society.