Construction of ZnFe₂O₄/rGO composites as selective magnetically recyclable photocatalysts under visible light...

This paper reports on highly active ZnFe₂O₄/reduced graphene oxide (ZnFe₂O₄/rGO) nanocomposites synthesized by a modified sol-gel method. The as-prepared samples have been characterized by XRD, TEM, XPS and other detection methods, which demonstrate that ZnFe₂O₄ nanoparticles (NPs) with a diameter of 15 ∼ 50 nm were densely grown on the rGO substrates. The photocatalytic activities of ZnFe₂O₄/rGO catalysts were evaluated by the degradation of Methylene blue (MB) under visible light. The results showed that the ZnFe₂O₄/rGO catalysts had high photocatalytic activity, and the degradation efficiency of MB was almost 100% within 180 min. Moreover, the ZnFe₂O₄/rGO catalysts also had a great removal effect on Rhodamine B (RhB) and Methyl orange (MO). Mechanistic studies revealed that the rGO acted as a stabilizer to prevent ZnFe₂O₄ from aggregation and improved the separation of photo-generated electrons. The high efficiency for dye degradation was attributed to the generation of hydroxyl radicals (·OH) via the photochemical decomposition of H₂O₂ on ZnFe₂O₄/rGO catalysts, which was responsible for the oxidation of the dyes. Of note, the ZnFe₂O₄/rGO catalyst maintained an efficiency of over 90% after five cycles. The XRD, XPS and VSM characterization revealed that the ZnFe₂O₄/rGO catalysts had a stable crystal structure and can be easily separated.