Related Experiment Video
Updated: Jan 27, 2026
Synthesis of Bimetallic Pt/Sn-based Nanoparticles in Ionic Liquids
Published on: August 23, 2018
Enhanced Luminescence Based Response towards pH in Highly Acidic Environments by the Silver Nanoparticles and Ionic
Hacer Esra Kabak1, Kadriye Ertekin2, Merve Zeyrek Ongun3
1The Graduate School of Natural and Applied Sciences, Department of Chemistry, University of Dokuz Eylul, 35160, Buca, Izmir, Turkey.
Abstract:
Correct measurement of the pH in highly acidic environments is still a challenge. In such conditions most of the pH indicators suffer from instability in air or leaching from host matrices due to the solubility considerations. In this work, two different fluorescent probes were used along with silver nanoparticles (AgNPs) and ionic liquid (IL) in the polymeric matrices for sensing of the pH in harsh conditions. The pH sensitivities of the probes were tested after exposure to strong acid vapors by steady-state, lifetime based and kinetic mode measurements. The sensing materials were fabricated in form of thin films and electrospun nanofibers. The ionic liquid; 1-butyl-3-methylimidazolium tetrafluoroborate was exploited as additive to enhance the stability as well as response towards pH. Spectral changes were tested in a large scale; between pH 3.00-12.00. Utilization of the dyes in ethyl cellulose and polymethyl methacrylate along with AgNPs in form of electrospun fibers resulted in many advantages such as enhanced long term stability, sensitivity and improvement in all sensor dynamics. Sensing characteristics of the offered designs were tested after exposed to vapors of HCl, H2SO4 and HNO3, respectively.
More Related Videos
Related Concept Videos
02:54Ions as Acids and Bases
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
00:42Ionic Bonds
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
02:55Solubility of Ionic Compounds
03:22Strong Acid and Base Solutions
03:10Ionic Radii
02:54Molecular and Ionic Solids
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...