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A route to a cyclobutane-linked double-looped system via a helical macrocycle
Jan Klajn1, Wojciech Stawski, Piotr J Chmielewski
1Wydział Chemii, Uniwersytet Wrocławski, F. Joliot-Curie 14, 50-383 Wrocław, Poland. milosz.pawlicki@chem.uni.wroc.pl.
Abstract:
Macrocycles built of carbazole and pyridine fragments with alkene/alkane linkers constitute a helical structure as documented structurally and spectroscopically. The 'solid-state' prearrangement observed for two C[double bond, length as m-dash]C bonds leads to unprecedented transformation to a cyclobutane in a head-to-tail (rtct) geometry with two macrocyclic loops in a perpendicular orientation.
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