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Published on: December 10, 2019
Fluorescence covalent interaction enhanced sensor for lead ion based on novel graphitic carbon nitride nanocones
Hanqiang Zhang1, Yihong Huang2, Yulin Zheng3
1School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, PR China; College of Chemistry and Materials, Longyan University, Longyan 364000, PR China.
Abstract:
Novel graphitic carbon nitride nanocones (g-CNNCs) were synthesized for the first time in this study. The SEM, TEM, XPS and FT-IR were used to research the structure of the g-CNNCs. We found that the g-CNNCs showed high selective and sensitive for fluorescence enhancement detection of Pb2+ ion via covalent interaction. In addition, the g-CNNCs exhibit stable and specific concentration-dependent fluorescence intensity in the presence of Pb2+ ion in the range of 1-200 μmol·dm-3, and the limit of detection was estimated to be 0.0438 μmol·dm-3 (3S/k). More importantly, the g-CNNCs were used to detect practical samples with satisfactory results.
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